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- 作者: 季甲,郭朝阳,雷文妮,郑佳苇,秦浩容,闫嘉红,侯银玲,辛晓艳,王文敏 ( 1凯里学院贵州省微介孔纳米材料制备与应用特色重点实验室;2太原师范学院化学与材料学院;3宁夏理工学院民航现代产业学院 )
- 出处: 1126 2025 第4期 P761-772
- 关键词: 双核Gd配合物 晶体结构 磁制冷 抑菌活性 DNA结合
- 摘要: 利用大共轭二酰腙有机配体N',N‴--双双与Gd·6HO 或Gd·2HO 反应,得到了2 例双核Gd 配合物:[Gd]·2CHOH·CHCN 和[Gd]·6CHCN 。结构研究表明,Gd配合物1 和2 均属于三斜晶系,空间群为P1,然而它们的分子结构却不同,其中1显示蒲扇形状,而2 为风车形状的笼子
期刊
- 作者: Jia-li Wang,Wen-Yu Li,Shu-Jie Wei,Xin-Ge Li,Yi-Jun Liu,Jing Wang,Yu Yao,Qin Wang,Wen-Min Wang ( 1These authors contributed equally to this work.;2College of Chemistry and Materials, Taiyuan Normal University, Jinzhong, Shanxi 030619, PR China )
- 出处: 132 2025 Vol.579 P122563
- 摘要: Herein, two polynuclear Ln-based clusters formulated as [YbL] and [YbL] have been obtained by using two different β-diketones via solvothermal meth
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- 作者: Feng-Jiao Chen,Yan-Ni Ling,Ke-Yi Wang,Yu-Qing Yao,Wen-Hui Chen,Ye Liu,Jin-Yu Zhao,Xiao-Yan Xin,Ying Shi,Wen-Min Wang ( 1College of Chemistry and Materials, Taiyuan Normal University, Jinzhong, Shanxi 030619, PR China;2These authors contributed equally to this work.;3Civil Aviation Modern Industry College, Ningxia Institute of Science and Technology, ShiZuiShan, NingXia 753000, PR China;4Shanxi Institute of Technology, Yangquan, Shanxi 045000, PR China )
- 出处: 436 2025 P117473
- 摘要: Two tetranuclear lantharide-based complexes: [Yb] and [Yb]·2CHCN -5-amino)-8-hydroxyquinoline; and HL = -5-amino)-8-hydroxyquinoline) were construct
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- 作者: Feng-Jiao Chen,Yan-Ni Ling,Ke-Yi Wang,Yu-Qing Yao,Wen-Hui Chen,Ye Liu,Jin-Yu Zhao,Xiao-Yan Xin,Ying Shi,Wen-Min Wang ( 1College of Chemistry and Materials, Taiyuan Normal University, Jinzhong, Shanxi 030619, PR China;2These authors contributed equally to this work.;3Civil Aviation Modern Industry College, Ningxia Institute of Science and Technology, ShiZuiShan, NingXia 753000, PR China;4Shanxi Institute of Technology, Yangquan, Shanxi 045000, PR China )
- 出处: 436 2025 Vol.272 P117473
- 摘要: Two tetranuclear lantharide-based complexes: [Yb] and [Yb]·2CHCN -5-amino)-8-hydroxyquinoline; and HL = -5-amino)-8-hydroxyquinoline) were construct
期刊
- 作者: Jia Ji,Han Wu,Yun-Xia Li,Lu-Yi Ma,Jing Lv,Yan-Ni Ling,Jia-Li Wang,Wen-Yu Li,Yin-Ling Hou,Xiao-Yan Xin,Wen-Min Wang ( 1School of Science, Kaili University, Kaili 556011, PR China;2Institute for Carbon Neutrality, Taiyuan Normal University, Jinzhong, Shanxi 030619, PR China;3Civil Aviation Modern Industry College, Ningxia Institute of Science and Technology, ShiZuiShan, NingXia 753000, PR China )
- 出处: 436 2024 Vol.262 P117165
- 摘要: A new tetranuclear Cu-based cluster with molecular formula [Cu] -methylidene]-3-methoxybenzoh-ydrazide) has been successfully synthesized by using so
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期刊
- 作者: Zhenjun Song, Mingyue Liu, Aiguo Zhong, Meiding Yang, Zhicai He, Wenmin Wang, Hongdao Li ( Affiliations 1 Engineering Research Center of Recycling & Comprehensive Utilization of Pharmaceutical and Chemical Waste of Zhejiang Province, School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000, China. 2 College of Chemistry and Materials, Taiyuan Normal University, Jinzhong 030619, China. 3 Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China. )
- 出处: 2741 2024 Vol.14 No.24 P2027
- 关键词: density-functional theory gold–magnesia interface guanine hydrolysis platinum compound.
- 摘要: Cisplatin-based platinum compounds are important clinical chemotherapeutic agents that participate in most tumor chemotherapy regimens. Through densit
期刊
- 作者: Zhenjun Song,Mingyue Liu,Aiguo Zhong,Meiding Yang,Zhicai He,Wenmin Wang,Hongdao Li ( 1Engineering Research Center of Recycling & Comprehensive Utilization of Pharmaceutical and Chemical Waste of Zhejiang Province, School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000, China;2College of Chemistry and Materials, Taiyuan Normal University, Jinzhong 030619, China;3Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China )
- 出处: 2884 2024 Vol.14 No.24 P2027
- 关键词: hydrolysis guanine gold–magnesia interface platinum compound density-functional theory
- 摘要: Cisplatin-based platinum compounds are important clinical chemotherapeutic agents that participate in most tumor chemotherapy regimens. Through densit
期刊
- 作者: Guan, Xiaofen,Liu, Yating,Li, Jia,Hu, Yiwen,Ding, Haiyuan,Shi, Yuanjing,Wang, Zhiqiang,Wang, Wenmin ( aCollege of Chemistry and Materials, Taiyuan Normal University, Shanxi, Jinzhong, 030619, China;bBasic Department, Shanxi Agricultural University, Shanxi, Jinzhong, 030801, China )
- 出处: 4032 2024 Vol.40 No.12 P2486-2496
- 关键词: binuclear lanthanide complexes crystal structures DNA insertion multidentate Schiff base
- 摘要: Two new dinuclear lanthanide complexes, namely [Ln]·4CHOH [Ln=Tb and Dy , Hdbm=dibenzoylmethane] have been synthesized using prepared multidentate Sc
- 作者: 关晓芬,刘娅婷,李佳,胡译文,丁海园,史原晶,王志强,王文敏 ( 1太原师范学院化学与材料学院;2山西农业大学基础部 )
- 出处: 1126 2024 第12期
- 关键词: 双核镧系配合物 晶体结构 多齿席夫碱 DNA 插入作用
- 摘要: 合成了具有良好生物活性的多齿席夫碱HL-肼),并以其为配体合成了2例双核镧系配合物[Ln]·4CHOH,其中Hdbm=二苯甲酰甲烷,Ln=Tb、Dy。结构表征显示该类配合物由2 个稀土金属离子与2个dbm配体,2个HL配体,2个配位的CHOH 分子以及4个游离的CHOH 分子组成。每个中心Ln为八配
期刊
- 作者: Cai-Long Xue,Xiao-Yan Xin,Yu Chang,Yang-Jun Gao,Jia-Yue Huang,Hong-Xue Qi,Ya-Jie Liu,Yong-Qiang Chen,Wen-Min Wang ( 1Department of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030619, P.R. China;2These authors contributed equally to this work.;3College of Biological Sciences and Technology, Taiyuan Normal University, Jinzhong, Shanxi 030619, P.R. China )
- 出处: 417 2023 P136058
- 摘要: Three new trinuclear lantharide-based compounds: [Ln]·CHCl , Sm, and Tb, dbm = diphthaloylmethae) have been synthesized via the solvothermal method by
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