Triplet Ground-State-Bridged Photochemical Process: Understanding the Photoinduced Chiral Inversion at the Metal Center of [Ru] and Its Bipy Analogues.
【作者单位】Affiliations 1 Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University , Taiyuan, Shanxi 030006, P. R. China. 2 Department of Chemistry, Taiyuan Normal University , Jinzhong, Shanxi 030619, P. R. China.
【年份】2017
【卷号】Vol.56 No.23
【页码】14467-14476
【ISSN】1520-510X
【摘要】 One of the main concerns in the photochemistry and photophysics of ruthenium complexes is the de-excitation of the triplet metal centered ligand-field state 3MC. To understand the mechanism by which the 3MC states in some reversible photochemical rea...
