【作者单位】1 Department of Chemistry, Taiyuan Normal University, Jinzhong 030619, China 2 Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education, The School of Chemical and Material Science, Shanxi Normal University, Linfen 041004, China 3 Humic Acid Engineering and Technology Research Center of Shanxi Province, Jinzhong 030619, China
【年份】2021
【卷号】Vol.762
【ISSN】0009-2614
【关键词】Hydrogen borrowing Iron catalysis Nitriles hydrogenation Secondary imines Theoretical investigation
【摘要】 The mechanism of Iron-catalyzed hydrogenation of nitriles involves two processes. • NH 3 -assisted H-migration greatly lowers the barriers in all the H-migration steps. • Theoretical mechanism well explains the experimental results. The mechanism of ...
