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A novel heterometallic [GdMn] cluster displaying larger cryogenic magnetocaloric effect

  • 【作者】Zhang, Shen,Wang, Wenmin Ming,Guo, Yan,Li, Chaoying,Guo, Yuyu,Hou, Yinling
  • 【刊名】Polyhedron
  • 【作者单位】a Department of Chemistry, Taiyuan Normal University, Jinzhong, 030619, China; b College of Arts, Taiyuan University of Technology, Jinzhong, 030024, China; c School of Life and Health Science, Kaili University, Kaili, 556011, China
  • 【年份】2020
  • 【卷号】Vol.191
  • 【ISSN】0277-5387
  • 【关键词】Cryogenic magnetocaloric effect Cubic-type tetranuclear core Magnetic property Structure Tetranuclear 3d-4f cluster 
  • 【摘要】 A 3d-4f cluster [Gd 2 Mn 2 2 L 4 4 ]·CH 3 CN was synthesized successfully, the structure and magnetical property of 1 were characterized and discussed. Cluster 1 possesses two defective cubic-type tetranuclear core which were connected by two μ 3...
  • 【文献类型】 期刊
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