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Synthesis, structures and magnetic refrigeration of two rhombus-shaped Gd4 cages.

  • 【作者】Guan, Xiao-Fen,Hou, Wen-Ying,Qiao, Xin-Yi,Zhang, Zhi-Qing,Liu, Ke-Xin,Wang, Wen-Ming,Shi, Ying,Pan, Fei
  • 【刊名】Inorganica Chimica Acta
  • 【作者单位】1 Department of Chemistry, Taiyuan Normal University, Jinzhong 030619, PR China
  • 【年份】2019
  • 【卷号】Vol.484
  • 【页码】47-51
  • 【ISSN】0020-1693
  • 【关键词】MAGNETIC cooling *CRYOGENIC gyroscopes *LIGANDS *STRUCTURAL analysis *ANTIFERROMAGNETIC materials 
  • 【摘要】 Graphical abstract Two Gd 4 clusters have been synthesized, structurally and magnetically characterized. Magnetic studies reveal that 1 and 2 display cryogenic magnetic refrigeration properties with −Δ S m = 21.95 J kg−1 K−1 for 1 (Δ H = 7 T and T = ...
  • 【文献类型】 期刊
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