Catalytic aerobic oxidation of carbohydrates to formic acid over HPVMoO: Rate relationships among catalyst reduction, catalyst re-oxidation and acid-catalyzed reactions and evidence for the Mars-van Krevelen mechanism
【作者单位】1State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China;2College of Chemistry and Materials, Taiyuan Normal University, Shanxi, 030619, China
【年份】2023
【页码】119055
【ISSN】0009-2509
【摘要】 Catalytic aerobic oxidation of biomass-derived carbohydrates is a promising way to sustainably produce formic acid. Understanding the rate relationships among catalyst reduction, catalyst re-oxidation and acid-catalyzed reactions occurring in catalyt...