Two dinuclear Gd‑based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity
【作者单位】aKey Laboratory of Preparation and Application of Micro & Mesoporous Nanomaterials of Guizhou Province, Kaili University, Guizhou, Kaili, 556011, China;bCollege of Chemistry and Materials, Taiyuan Normal University, Shanxi, Jinzhong, 030619, China;cCivil Aviation Modern Industry College, Ningxia Institute of Science and Technology, Ningxia, Shizuishan, 753000, China
【年份】2025
【卷号】Vol.41 No.4
【页码】761-772
【ISSN】1001-4861
【关键词】antibacterial activity crystal structure dinuclear Gd complexes DNA binding magnetic refrigeration
【摘要】 Two new binuclear Gd complexes with the molecular formula [Gd]·2CHOH·CHCN and [Gd]·6CHCN have been obtained by using a large conjugated diacylhy- drazone organic ligand N',N‴--bis bis reacting with Gd·6HO or Gd·2HO. Structure studies reveal that...