【作者单位】1 The School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, PR China 2 Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, PR China 3 Scientific Instrument Center, Shanxi University, Taiyuan 030006, PR China
【摘要】 Treatment of a secondary amine (piperidine or N -benzylmethylamine) with sequentially trimethylaluminum and carbodiimide CyN C NCy in a molar ratio of 1:1:1 afforded two mononuclear guanidinatoaluminum complexes, [{(C 5 H 10 N)C(NCy) 2 }AlMe 2 ] ( 1 ...