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Synthesis and crystal structures of guanidinatoaluminum complexes and catalytic study for MPV reduction.

  • 【作者】Han, Hongfei,Guo, Zhiqiang,Zhang, Shaofeng,Hua, Yupeng,Wei, Xuehong
  • 【刊名】Polyhedron
  • 【作者单位】1 The School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, PR China 2 Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, PR China 3 Scientific Instrument Center, Shanxi University, Taiyuan 030006, PR China
  • 【年份】2017
  • 【卷号】Vol.126
  • 【页码】214-219
  • 【ISSN】0277-5387
  • 【关键词】CRYSTAL structure *ALUMINUM *METAL complexes *CHEMICAL reduction *CATALYTIC activity 
  • 【摘要】 Treatment of a secondary amine (piperidine or N -benzylmethylamine) with sequentially trimethylaluminum and carbodiimide CyN C NCy in a molar ratio of 1:1:1 afforded two mononuclear guanidinatoaluminum complexes, [{(C 5 H 10 N)C(NCy) 2 }AlMe 2 ] ( 1 ...
  • 【文献类型】 期刊
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