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Three asymmetric guanidinato metal complexes: Synthesis, crystal structures and their use as pre-catalysts in the Meerwein–Ponndorf–Verley reduction

  • 【作者】Hong-Fei Han,Shao-Feng Zhang,Zhi-Qiang Guo,Hong-Bo Tong,Xue-Hong Wei
  • 【刊名】Polyhedron
  • 【作者单位】a The School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, PR China b Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, PR China c Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, PR China
  • 【年份】2015
  • 【卷号】Vol.99
  • 【页码】71-76
  • 【ISSN】0277-5387
  • 【关键词】Guanidinato compounds Synthesis Crystal structure Meerwein–Ponndorf–Verley reduction Precatalytic use 
  • 【摘要】 The guanidinatolithium compound [{(C 2 H 5 ) 2 N}C(NC 6 H 5 )(NAr)LiOEt 2 ] 2 (Ar = 2,6-Me 2 C 6 H 3 ) (1), is readily accessible in high yield upon insertion reaction of lithium diethyl amide with unsymmetric carbodiimine ArN C NC 6 H 5 . The...
  • 【文献类型】 期刊
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