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Synthesis, Characterization, and Crystal Structure of Two Novel Diiron Dithiolate Complexes Bearing Thiolate-Bridged-Carboxy Functionality

  • 【作者】Han, Hong-Fei,Xiong, Kuan-Kuan,Zhao, Pei-Hua
  • 【刊名】Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
  • 【作者单位】1 Department of Chemistry, Taiyuan Normal University, Taiyuan, P. R. China 2 School of Materials Science and Engineering, North University of China, Taiyuan, P. R. China
  • 【年份】2016
  • 【卷号】Vol.46 No.8
  • 【页码】1260-1264
  • 【ISSN】1553-3174
  • 【关键词】diiron dithiolate complexes thiolate-bridged-carboxy functionality synthesis crystal structure 
  • 【摘要】 Two new diiron dithiolate complexes [(μ-SCH 2 ) 2 CHCO 2 R][Fe 2 (CO) 6 ] (R = -C 10 H 7 -β, 1; -C 6 H 4 Me-m, 2) bearing thiolate-bridged-carboxy functionality, which are closely related to the active site of [FeFe]-hydrogenase, have been synthesize...
  • 【文献类型】 期刊
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