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Two linear-shaped Gd clusters based on a multidentate ligand: Synthesis, structures, and magnetic refrigeration

  • 【刊名】Polyhedron
  • 【作者单位】a School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, 273165, China; b Shandong Provincial Key Laboratory of Detection Technology for Tumor Markers, School of Chemistry and Chemical Engineering, Linyi University, Linyi, 276000, China; c Department of Chemistry, Taiyuan Normal University, Jinzhong, 030619, China
  • 【年份】2019
  • 【卷号】Vol.169
  • 【页码】247-252
  • 【ISSN】0277-5387
  • 【关键词】Antiferromagnetic interactions Cryogenic magnetocaloric effects Linear-shaped clusters Multidentate ligand HL Tetranuclear gadolinium clusters 
  • 【摘要】 Two novel and tetranuclear gadolinium clusters, namely, [Gd 4 2 6 2 ]and [Gd 4 2 6 2 ]-N′--methylene)picolinohydrazide and dbm = dibenzoylmethane), were assembled by the reaction of a multidentate ligand H 3 L with Gd 3 ·2H 2 O in different sol...
  • 【文献类型】 期刊
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