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Large magnetocaloric effect and remarkable single-molecule-magnet behavior in triangle-assembled Ln III 6 clusters

  • 【作者】Wang, W.-M.,Yue, R.-X.,Gao, Y.,Wang, M.-J.,Hao, S.-S.,Shi, Y.,Kang, X.-M.,Wu, Z.-L.
  • 【刊名】New Journal of Chemistry
  • 【作者单位】a Department of Chemistry, Taiyuan Normal University, Jinzhong, 030619, China; b Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, China; c Department of Biology, Taiyuan Normal University, Jinzhong, 030619, China
  • 【年份】2019
  • 【卷号】Vol.43 No.42
  • 【页码】16639-16646
  • 【ISSN】1144-0546;1369-9261
  • 【摘要】 Two new and interesting polynuclear lanthanide clusters, namely, [Ln 6 4 2 4 2 ]·2CH 3 OH and Dy , Hacac = acetylacetone, H 3 L = N′--6-picolinohydrazide and THAM = trismethylaminomethane), were assembled by using a polydentate ligand reacting ...
  • 【文献类型】 期刊
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