Four Ln compounds constructed by a polydentate Schiff base ligand: Gd compound displaying large magnetocaloric effect and Dy compound showing single-molecule magnet behavior
【作者单位】1 Department of Chemistry, Taiyuan Normal University, Jinzhong 030619, PR China; 2 Ordos Institute of Technology, Ordos 017000, Inner Mongolia, PR China; 3 Department of Chemistry, Hebei Normal University of Science & Technology, Qinhuangdao 066004, PR China
【摘要】 Four new acyloxy bridged Ln III 2 compounds [Ln 2 2 2 2 ] = Gd , Tb , Dy , and Ho , Hacac = acetylacetone, and H 2 L = pyridine-2-carboxylic acid -hydrazide) have been prepared by a polydentate Schiff base ligand under solvothermal condition. T...