【作者单位】1College of Chemistry and Materials, Taiyuan Normal University, Jinzhong, 030619, China;2College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin, 300457, China;3These two authors contributed equally to this work.
【年份】2022
【ISSN】1002-0721
【关键词】Wheel-shaped Ln clusters Conversion of CO Magnetocaloric effect Single-molecular magnet behavior Rare earths
【摘要】 A series of novel hexanuclear lanthanide clusters, namely, [Ln]·3CHCN , Tb, Dy and Er) were assembled using a multidentate ligand HL . The clusters 1–4 show a wheel-shaped Ln topology with the approximate diameter and thickness of 1.5 and 0.7 nm, res...
