Impacts of coordination modes of PNP-diphosphine ligands on the redox and electrocatalytic properties of diiron oxadithiolate complexes for proton reduction.

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【作者】Zhao, Pei-Hua，Hu, Meng-Yuan，Li, Jian-Rong，Wang, Yan-Zhong，Lu, Bao-Ping，Han, Hong-Fei，Liu, Xu-Feng
【刊名】Electrochimica Acta
【作者单位】1 School of Materials Science and Engineering, North University of China, Taiyuan 030051, PR China 2 Department of Chemistry, Taiyuan Normal University, Jinzhong 030619, PR China 3 School of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, PR China
【年份】2020
【卷号】Vol.353
【ISSN】0013-4686
【关键词】Coordination modes Diiron oxadithiolate complexes Electrocatalytic proton reduction PNP-Diphosphine ligands Protonation
【摘要】 As diiron subsite models of [FeFe]-hydrogenases with odt bridge, two new series of PNP-chelate or -bridge diiron oxadithiolate complexes Fe 2 4 { 2 NR} were prepared by selective substitutions of diiron hexacarbonyl complex Fe 2 6 with different ...
【文献类型】期刊