【作者单位】1 International Collaborative Research Center of Tianjin for Food Nutrition, Safety and Medicinal Chemistry, College of Biotechnology, Tianjin University of Science & Technology 2 Department of Chemistry, Taiyuan Normal University 3 Department of Chemistry, Louisiana State University 4 Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University
【年份】2017
【卷号】Vol.30 No.1
【ISSN】0894-3230
【关键词】annulation Curtin-Hammet principle density functional calculations diastereoselectivity reaction mechanisms
【摘要】 Computational studies on the mechanism and diastereoselectivity of base catalyzed synthesis of bicyclo[3.3.1]nonanes by are reported. Three possible mechanisms were considered, and only the methanol assisted H-shift process could be the favorable pat...
