【作者单位】1 International Collaborative Research Center of Tianjin for Food Nutrition, Safety and Medicinal Chemistry, College of Biotechnology, Tianjin University of Science & Technology, Tianjin 300457, China 2 Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, China 3 Canyon View Ave., Cody WY, 82413, USA 4 6th Street, Cody WY, 82414, USA 5 Department of Chemistry, Louisiana State University, Baton Rouge LA, 70803, USA 6 Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China
【摘要】 Computational studies on the mechanism and diastereoselectivity of base catalyzed synthesis of bicyclo[3.3.1]nonanes by are reported. Three possible mechanisms were considered, and only the methanol assisted H-shift process could be the favorable pat...