【作者】Dong Wang，Longfei Miao，Lixia Feng，Qingwei Yao，Gnel Mkrtchyan，William E. Crowe，Evgueni E. Nesterov，Yuekui Wang，Xiaoting Zhang，Peng Yu
【刊名】Journal of Physical Organic Chemistry
【作者单位】1Current address: China International Science and Technology Cooperation Base of Food Nutrition/Safety and Medicinal Chemistry, Sino‐French Joint Lab of Food Nutrition/Safety and Medicinal Chemistry, College of Biotechnology, Tianjin University of Science & Technology, Tianjin 300457, China;2International Collaborative Research Center of Tianjin for Food Nutrition, Safety and Medicinal Chemistry, College of Biotechnology, Tianjin University of Science & Technology, Tianjin, 300457, China;3Department of Chemistry, Taiyuan Normal University, Taiyuan, 030031, China;426 Canyon View Ave., Cody, WY, 82413, USA;5513 6th Street, Cody, WY, 82414, USA;6Department of Chemistry, Louisiana State University, Baton Rouge, LA, 70803, USA;7Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University, Taiyuan, 030006, China
【年份】2017
【卷号】Vol.30 No.1
【页码】62-66
【ISSN】0894-3230
【关键词】annulation Curtin–Hammet principle density functional calculations diastereoselectivity reaction mechanisms
【摘要】 Computational studies on the mechanism and diastereoselectivity of base catalyzed synthesis of bicyclo[3.3.1]nonanes by Robinson annulation are reported. Three possible mechanisms were considered, and only the methanol assisted H‐shift process could ...
