【作者】Dong Wang，Longfei Miao，Lixia Feng，Qingwei Yao，Gnel Mkrtchyan，William E. Crowe，Evgueni E. Nesterov，Yuekui Wang，Xiaoting Zhang，Peng Yu
【刊名】Journal of Physical Organic Chemistry
【作者单位】1 International Collaborative Research Center of Tianjin for Food Nutrition, Safety and Medicinal Chemistry, College of Biotechnology, Tianjin University of Science & Technology, Tianjin, China 2 Department of Chemistry, Taiyuan Normal University, Taiyuan, China 3 Cody, WY, USA 4 Cody, WY, USA 5 Department of Chemistry, Louisiana State University, Baton Rouge, LA, USA 6 Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University, Taiyuan, China
【年份】2017
【卷号】Vol.30 No.1
【ISSN】0894-3230
【关键词】annulation Curtin-Hammet principle density functional calculations diastereoselectivity reaction mechanisms
【摘要】 Computational studies on the mechanism and diastereoselectivity of base catalyzed synthesis of bicyclo[3.3.1]nonanes by Robinson annulation are reported. Three possible mechanisms were considered, and only the methanol assisted H-shift process could ...
