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Successive C1–C2 bond cleavage: the mechanism of vanadium(V)-catalyzed aerobic oxidation of D-glucose to formic acid in aqueous solution

  • 【作者】Muge Niu,Yucui Hou,Weize Wu,Shuhang Ren,Ru Yang
  • 【刊名】Physical Chemistry Chemical Physics
  • 【作者单位】Corresponding authors ; a State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China E-mail: wzwu@mail.buct.edu.cn Fax: +86 10 64427603 Tel: +86 10 64427603 ; b Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, P. R. China ; c College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, P. R. China
  • 【年份】2018
  • 【卷号】Vol.20 No.26
  • 【页码】17942-17951
  • 【ISSN】1463-9076;1463-9084
  • 【摘要】 Vanadium(V)-catalyzed aerobic oxidation in aqueous solution shows high selectivity in the field of C–C bond cleavage of carbohydrates for chemicals with less carbon atoms. However, the pathway of C–C bond cleavage from carbohydrates and the conversio...
  • 【文献类型】 期刊
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