Triplet Ground-State-Bridged Photochemical Process: Understanding the Photoinduced Chiral Inversion at the Metal Center of [Ru(phen)2(l -ser)]+ and Its Bipy Analogues(Article)
【作者单位】a Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Institute of Molecular Science, Shanxi University, Taiyuan, Shanxi, China; b Department of Chemistry, Taiyuan Normal University, Jinzhong, Shanxi, China
【年份】2017
【卷号】Vol.56 No.23
【页码】14467-14476
【ISSN】0020-1669
【摘要】 One of the main concerns in the photochemistry and photophysics of ruthenium complexes is the de-excitation of the triplet metal centered ligand-field state 3 MC. To understand the mechanism by which the 3 MC states in some reversible photochemical...
