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Synthesis and Crystal Structure of a New Guanidinatoaluminium Complex and Its Utility in the Meerwein-Ponndorf-Verley Reduction

  • 【作者】HAN HongFei,LI WenJuan,ZHANG ShaoFeng,WEI XueHong
  • 【刊名】结构化学
  • 【作者单位】Department of Chemistry,Taiyuan Normal University;The School of Chemistry and Chemical Engineering,Shanxi University;Scientific Instrument Center,Shanxi University
  • 【年份】2018
  • 【卷号】第37卷
  • 【期号】 第4期
  • 【页码】624-630
  • 【ISSN】0254-5861
  • 【关键词】guanidinatoaluminium complex synthesis crystal structure MPV reaction 
  • 【摘要】 The treatment of pyrrolidine(C4H8NH) with sequentially trimethylaluminum and carbodiimide Cy N=C=NCy in a molar ratio of 1:1:1 in the presence of O2 afforded a new guanidinatoaluminum complex, [{(C4H8N)C(NCy)2}Al Me(μ-OMe)]2(1), which was characteriz...
  • 【文献类型】 期刊
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