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A theoretical elucidation for the formation of unusual zwitterionic sandwich and terminal ruthenium complexes.

  • 【作者】Huo, Rui‐Ping,Zhang, Xiang,Zhang, Cai‐Feng
  • 【刊名】Journal of Physical Organic Chemistry
  • 【作者单位】1 Department of Chemistry, Taiyuan Normal University, Jinzhong, China 2 Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education, The School of Chemical and Material Science, Shanxi Normal University, Linfen, China 3 Humic Acid Engineering and Technology Research Center of Shanxi Province, Jinzhong, China
  • 【年份】2020
  • 【卷号】Vol.33 No.9
  • 【页码】1-8
  • 【ISSN】0894-3230
  • 【关键词】cyanamido M11 ruthenium sandwich zwitterionic complex 
  • 【摘要】 The transformation mechanism of the ruthenium azido isocyanide [CpMe5Ru2N3] toward cyanamido ruthenium complexes was investigated by M11 calculations. Coordination‐unsaturated complex CpMe5Ru‐CNAr , coordination‐saturated complex CpMe5Ru‐CNAr , and ...
  • 【文献类型】 期刊
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