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A theoretical elucidation for the formation of unusual zwitterionic sandwich and terminal ruthenium complexes

  • 【作者】Huo, R.-P.,Zhang, X.,Zhang, C.-F.
  • 【刊名】Journal of Physical Organic Chemistry
  • 【作者单位】a Department of Chemistry, Taiyuan Normal University, Jinzhong, China; b Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education, The School of Chemical and Material Science, Shanxi Normal University, Linfen, China; c Humic Acid Engineering and Technology Research Center of Shanxi Province, Jinzhong, China
  • 【年份】2020
  • 【ISSN】0894-3230
  • 【关键词】cyanamido M11 ruthenium sandwich zwitterionic complex 
  • 【摘要】 The transformation mechanism of the ruthenium azido isocyanide [CpMe 5 Ru 2 N 3 ] toward cyanamido ruthenium complexes was investigated by M11 calculations. Coordination-unsaturated complex CpMe 5 Ru-CNAr , coordination-saturated complex CpMe 5 Ru-C...
  • 【文献类型】 期刊
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