Impacts of coordination modes of PNP-diphosphine ligands on the redox and electrocatalytic properties of diiron oxadithiolate complexes for proton reduction
【作者】Pei-Hua Zhao，Meng-Yuan Hu，Jian-Rong Li，Yan-Zhong Wang，Bao-Ping Lu，Hong-Fei Han，Xu-Feng Liu
【刊名】Electrochimica Acta
【作者单位】b Department of Chemistry, Taiyuan Normal University, Jinzhong 030619, PR China a School of Materials Science and Engineering, North University of China, Taiyuan 030051, PR China c School of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, PR China
【摘要】 As diiron subsite models of [FeFe]-hydrogenases with odt bridge, two new series of PNP-chelate or -bridge diiron oxadithiolate complexes Fe 2 4 { 2 NR} were prepared by selective substitutions of diiron hexacarbonyl complex Fe 2 6 with different...
